Enhanced catalytic performance for direct synthesis of dimethyl ether from syngas over a La2O3 modified Cu--ZrO2/γ-Al2O3 hybrid catalyst

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发表刊物:JOURNALOF NATURALGAS CHEMISTRY

关键字:dimethylether;syngas;hybridcatalyst;Cu—ZrO2;La2O3

摘要:A series of hybrid catalysts were made by physically mixing Cu-ZrO2 and γ-A12O3, for former it was modified with diferent loadings of La2O3 prepared by co-precipitation method. The catalysts were characterized by BET, XRD, N2O-adsorption, EXAFS, H2-TPR, NH3-TPD techniques and evaluated in the synthesis of dimethyl ether from syngas. The results show that La2O3 promoted catalysts displayed a significantly better catalytic performance compared with Cu-ZrO2/γ-A12O3 catalyst in CO conversion and DME selectivity, and the optimum catalytic activity was obtained when the content of La2O3 was......

合写作者:Zhuo Li; Jianqing Li; Cheng Yang; Jinhu Wu

通讯作者:Cheng Yang

文献类型:J

卷号:21

页面范围:360-365

ISSN号:2053-1591

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收录刊物:SCI

发布期刊链接:www.elsevier.com/locate/jngc